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Have her check out:
http://Corneredcat.com.

I don't know how your wife is, but the "trick" with mine is somehow get her to think things I want are her ideas. (She pulls the same trick on me and it works great!)

My wife is mostly gun agnostic, leaning toward pro gun. I'd have a nice, non-confrontational talk with your wife, and try and find out what her fears are. Once you know what her fears really are, you can nip 'em in the bud.

The biggest hurdle was getting HER to realize the intracies of everything. "That sign says no guns, you better go put yours away!" and the like.