Over the weekend, I got a pile of assorted loaded rounds at the range where I pick up brass. These are OLD rounds, some of which laid outside for indeterminate amounts of time, some of which were obviously immersed in water for a while, and some plain old obscure calibers: .32-20 (and .32 WCF), .257 Roberts (which I only know by it's name), .38 Long, .35 Remington, and a few more 'normal' rounds. I say that these are obscure simply because they aren't in widespread use these days.
Anyhow, Question #1: What is this rimfire round? Anyone know? It has a "U" on the headstamp, and is I-don't-know how old. It is obviously a .22 caliber rimfire of some sort, but I'll be hanged if I can find it anywhere. Compared to a .22 LR, it measures thusly:
.22 LR Unknown
Bullet: .224 .224
Case: .224 .250 (at rim), .244 (at 'cannelure')
Rim: .272 .312
OAL: .974 .911


It was in the mix with this batch of 'stuff'. Was there ever a military rifle chambered in .257 Roberts? If not, why the stripper clip and 'web belt' that is full of them? Or was that just handy storage?

Question #2: As I pull the bullets on these and sprinkle the powder on the plants, how should I render the primers inert? Water? Hammer? Oil? Magic? The brass will be recycled, but I'm not putting live primers in the recycle bucket.
Question #3: The guy I get the brass from has a few hundred of these boxes, both .38 SPL and .357 Magnum. They all have fired brass in them, none are empty, and none are filled with loaded rounds, just the original boxes with the fired brass that used to be loaded in them. Is there a market for boxes with fired brass, or is the value in the boxes only, or in the boxes filled with loaded rounds?

As usual, I appreciate any light y'all can shed on these things.